Masses which may be cross-linked to give elastomers with cleavage of alcohols from alkoxysilyl end groups

ABSTRACT

Storage stability of one-component elastomers prepared from constituents having alkoxysilyl end groups is enhanced by employing bin compounds having a coordination number of 5 or 6 in which tin is coordinately bonded to a P═O group as at least one condensation catalyst.

[0001] The invention relates to compositions which are crosslinkable with elimination of alcohols from alkoxysilyl end groups to give elastomers, and which comprise a tin catalyst (T), in which the catalyst present comprises a tin compound (T) having a coordination number of 5 or 6.

[0002] Compositions crosslinkable with elimination of alcohols from alkoxysilyl end groups to give elastomers, for example single-component organopolysiloxane compositions crosslinkable with elimination of alcohols to give elastomers (RTV1 alkoxy compositions), need catalysts for the crosslinking process.

[0003] The use of dialkyltin(IV) compounds as condensation catalysts in RTV1 and RTV2 silicone rubbers is well known. However, in RTV1 alkoxy compositions these tin compounds have the disadvantage that they likewise catalyze an undesired cleavage of the siloxane chains by traces of alcohol (equilibration). These small amounts of alcohol arise during the compounding process through hydrolysis of the alkoxysilanes used as crosslinking agents, by water entrained by the raw materials. The equilibration process produces monoalkoxy end groups on the polysiloxane chain, and these can no longer be crosslinked. The result is prevention of adequate crosslinking of the composition, with the result that correct use of the material either does not give a vulcanizate or at least gives a vulcanizate with inadequate mechanical stability. The equilibration process drastically reduces storage stability, stated in terms of the period for which the RTV1 alkoxy composition can be stored without discernible loss of its properties.

[0004] Similar problems are also found with other systems crosslinkable with elimination of alcohols to give elastomers, for example with polyethers having alkoxysilyl end groups. Here again, the dialkyltin(IV) compounds used as condensation catalysts cause storage stability problems, which are suppressed by a particularly inconvenient preparation process, for example baking the polymer/filler mixtures in vacuo for some hours.

[0005] Various methods have been developed to improve storage stability in RTV1 alkoxy compositions. As a first example, EP-A-69 256 attempts to eliminate the traces of alcohol by adding compounds which react irreversibly with the alcohol. These compounds are termed scavengers.

[0006] Furthermore, attempts have also been made to prepare scavenger-free mixtures. The titanium catalysts or zirconium catalysts described in U.S. Pat. No. 5,674,936 are particularly suitable for this purpose. However, a decisive disadvantage associated with these catalysts is that they either have a strong tendency toward yellowing or indeed have a yellow intrinsic color. This prevents the preparation of transparent, colorless RTV1 mixtures. However, it is specifically these mixtures which are most in demand, because they have universal application.

[0007] The use of compounds having Sn—O—P bonds, obtained from diesters of phosphoric acid, is also known, for example from U.S. Pat. No. 3,525,778.

[0008] However, the tin catalysts known from the literature give rise to the polymer degradation reactions described above when they are used in polysiloxane compositions. This is seen, for example, in the loss, or retarding, of the crosslinkability of RTV1 products.

[0009] A further improvement is provided by the use, described in U.S. Pat. No. 6,162,756, of catalysts having Sn—O—P bonds, obtained by reaction of monoesters of phosphoric acid with organic tin compounds. However, it has been found that the very high acid number of the phosphorus compounds used, resulting from the restriction of the invention to the use of monoesters of phosphoric acid, which have to be used at least in amounts equimolar with the tin compound, or in excess, causes problems with storage stability and adhesion problems, these being particularly evident when the adhesive bonds are aged in water.

[0010] The invention is based on the object of providing catalysts for compositions which have good storage stability, which need no scavenger, and which are crosslinkable with elimination of alcohols from alkoxysilyl end groups to give elastomers.

[0011] The invention provides compositions which are crosslinkable with elimination of alcohols from alkoxysilyl end groups to give elastomers, and which comprise a tin catalyst (T), and in which the catalyst present is a tin compound (T) having a coordination number of 5 or 6, in which the tin atom has coordinate bonding to the P═O group of a phosphorus compound having a P═O group, the tin compound (T) being obtainable via reaction of a phosphorus compound having a P═O group and selected from compounds of the general formula (I)

O═PR¹ _(m)(OR²)_(n)(OH)_(3-m-n)  (I)

[0012] where

[0013] n is the values 2 or 3, if m has the value 0,

[0014] n is the values 0, 1, or 2, if m has the values 1, 2, or 3,

[0015] m+n is the values 1, 2, or 3,

[0016] R¹ and R² are C₁-C₃₀-hydrocarbon radicals, which may have substitution by hydroxy, halogen, or cyano radicals, or radicals of the general formula (II)

[(CR³ ₂)_(b)—O]_(c)(CR⁴ ₂)_(d)-L-M  (II)

[0017] where

[0018] R³ and R⁴ are a hydrogen radical, methyl radical, or hydroxy radical,

[0019] b and d are the values 2 or 3,

[0020] c is integral values from 1 to 15,

[0021] L is a radical from the group —O—, —COO—, —OOC—, —CONR⁵—, —NR⁶CO—, and —CO—,

[0022] R⁵ and R⁶ are a hydrogen radical or a C₁-C₁₀-alkyl radical, and

[0023] M is a monovalent C₁-C₂₀-hydrocarbon radical, unsubstituted or substituted with hydroxy, fluoro, chloro, bromo, C₁-C₁₀-alkoxyalkyl, or cyano groups, with the proviso that on each carbon atom only one of the radicals R³ and R⁴ may be a hydroxy radical, compounds of the general formula (III)

O═PR⁷ _(o)(NR⁸ ₂)_(p)(OR⁹)_(3-o-p)  (III),

[0024] where

[0025] R⁷ is as defined for R¹,

[0026] R⁸ is as defined for R¹, where it is also possible for the two radicals R⁸ to have bonding to one another,

[0027] R⁹ is as defined for R¹, or is hydrogen,

[0028] o is the values 0, 1, or 2,

[0029] p is the values 1, 2, or 3, and

[0030] o+p is the values 1, 2, or 3,

[0031]  and condensates or hydrolysates of compounds of the general formulae (I) to (III) having one or more P—O—P bonds,

[0032]  with an organic tin compound which is selected from a compound of the general formula (IV)

R¹⁰ _(4-r)SnX_(r)  (IV),

[0033]  a compound of the general formula (V)

R¹⁰ ₂SnY  (V),

[0034]  a compound of the general formula (VI)

R¹⁰ ₃SnY_(1/2)  (VI),

[0035]  and a compound of the general formula (VII)

R¹⁰SnY_(3/2)  (VII),

[0036] where

[0037] R¹⁰ is C₁-C₃₀-hydrocarbon radicals, which may have substitution by halogen radicals or by cyano radicals,

[0038] X is halo, —OH, —OR¹⁰, —SR¹⁰, —OOCR¹⁰, —NR¹⁰ ₂, —NHR¹⁰, —OSiR¹⁰ ₃ or —OSi(OR¹⁰)₃,

[0039] Y is O or S, and

[0040] r is the values 1, 2, or 3.

[0041] The compositions crosslinkable to give elastomers have good storage stability.

[0042] In the tin compound (T), the tin atom has coordinate bonding to the phosphorus compound having the P═O group. A covalent bonds between the phosphorus compound and the tin atom is not a requirement, but may be present. The result is that the tin compound (T) remains capable of catalyzing the condensation reaction at the alkoxysilyl end groups.

[0043] However, at the same time the alcohol present in the compositions is is not sufficiently activated to enter into disruptive reactions which could reduce storage stability.

[0044] The phosphorus compound used of the general formula (I) are, for example tributyl phosphate, tris(butoxyethyl) phosphate, tris (lauryltriethylene glycol)phosphate, bis(lauryltriethylene glycol)phosphate triphenylphosphine oxide, bis(aryl or alkyl)hydoxymethylphosphonic acid, or phenylphosphonic acid.

[0045] Preference is given to the triesters of orthophosphoric acid.

[0046] Examples of a phosphorus compound used of the general formula (III) are, by way of example, hexamethylphosphoramide or tripiperidinophosphine oxide.

[0047] Examples of the organic tin compounds of the general formulae (IV) to (VII) are DBTA, DBTL, or reaction products of DBTA, DBTL, and/or DBTO with alkoxysilanes, and it is also possible for the conversion of the materials to begin only when they are in situ in the composition which is crosslinkable to give elastomers.

[0048] The tin catalyst (T) may be prepared by reaction of the phosphorus compound used, selected from compounds of the general formulae (I) and (III), with an organic tin compound selected from a compound of the general formula (IV) to (VII) prior to addition to the composition crosslinkable to give elastomers, or only after addition to the composition.

[0049] The compositions crosslinkable to give elastomers are any desired compositions which are crosslinkable with elimination of alcohols from alkoxysilyl end groups to give elastomers. Examples of these are compositions based on compounds having alkoxysilyl end groups, these being organopolysiloxanes, polyethers, polyesters, polyurethanes, polyureas, and copolymers of organopolysiloxanes, polyethers, polyesters, polyurethanes, and polyureas. Preference is given to organopolysiloxane compositions crosslinkable with elimination of alcohols to give elastomers, in particular single-component organopolysiloxane compositions (RTV1 alkoxy compositions).

[0050] The use of the tin catalysts (T) improves the adhesion to various substrates of the single-component organopolysiloxane compositions crosslinkable with elimination of alcohols to give elastomers (RTV1 alkoxy compositions).

[0051] RTV1 alkoxy compositions preferably comprise organopolysiloxane (A) terminated by alkoxy groups, in particular linear diorganosiloxanes of the general formula (VIII)

R¹¹ _(f)(R¹²O)_(3-f)Si—(O—SiR₂)_(g)—O—SiR¹¹ _(f)(OR¹²)_(3-f)  (VIII)

[0052] where

[0053] each of R, R¹¹ and R¹² is a monovalent C₁-C₈-hydrocarbon radical, unsubstituted or substituted with fluoro, chloro, bromo, C₁-C₄-alkoxyalkyl, or cyano groups,

[0054] f is the values 0 or 1, and

[0055] g is values corresponding to a viscosity of from 0.05 to 1 000 Pa.s for the organopolysiloxane (A).

[0056] Preferred radicals R, R¹¹, and R¹² are unsubstituted C₁-C₄-alkyl radicals, the methyl radical being particularly preferred.

[0057] The viscosity of the organopolysiloxane (A) is preferably from 100 to 70 000 mPa.s, in particular from 20 000 to 350 000 mPa.s, in each case measured at 23° C.

[0058] The RTV1 alkoxy compositions preferably comprise at least 35% by weight, in particular at least 45% by weight, and preferably at most 80% by weight, in particular at most 70% by weight, of organopolysiloxane (A).

[0059] The the RTV1 alkoxy compositions preferably comprise alkoxysilanes (B), which in particular have the general formula (IX)

R¹³ _(μ)Si(OR¹⁴)_(4-μ)  (IX)

[0060] where

[0061] R¹³ and R¹⁴ are monovalent C₁-C₁₃-hydrocarbon radicals, unsubstituted or substituted with fluoro, chloro, bromo, C₁-C₄-alkoxy alkoxyalkyl, or cyano groups, and

[0062] μ is the values 0 or 1.

[0063] Partial hydrolysates of alkoxysilane (B), arising via hydrolysis and condensation of, in particular, from 2 to 4 alkoxysilanes may also be present.

[0064] Examples of partial hydrolyzates (B) are hexamethoxydisiloxane and hexaethoxydisiloxane.

[0065] R¹³ is preferably unsubstituted C₁-C₆-hydrocarbon radicals, in particular methyl, ethyl, and propyl radicals.

[0066] R¹⁴ is preferably unsubstituted C₁-C₆-hydrocarbon radicals, in particular methyl, ethyl, vinyl, and propyl radicals.

[0067] The RTV1 alkoxy compositions preferably comprise at least 0.01% by weight, in particular at least 0.1% by weight, and preferably at most 3% by weight, in particular at most 1% by weight, of tin catalyst (T).

[0068] In addition to the abovementioned components, the RTV1 alkoxy compositions may comprise other components known per se, such as crosslinking agents, fillers, pigments, soluble dyes, fragrances, plasticizers, fungicides, resin-like organopolysiloxanes, including those composed of (CH₃)₃SiO_(1/2) units and of SiO_(4/2) units, purely organic resins, such as homo- or copolymers of acrylonitrile, of styrene, of vinyl chloride, or of propylene, where these purely organic resins, in particular copolymers of styrene and n-butyl acrylate, may have been produced in the presence of diorganopolysiloxane having a Si-bonded hydroxy group in each of the terminal units, via free-radical polymerization of the monomers mentioned, corrosion inhibitors, oxidation inhibitors, heat stabilizers, solvents, agents affecting electrical properties, for example conductivity black, flame retardants, light stabilizers, and agents to prolong skinning time, for example silanes having Si—C-bonded mercaptoalkyl radicals, or else cell formers, e.g. azodicarbonamide. Coupling agents may also be added.

[0069] The RTV1 alkoxy compositions preferably comprise fillers. Examples of fillers are non-reinforcing fillers, i.e. fillers whose BET surface area is up to 50 m²/g, for example chalks with a carboxylic acid coating, quartz, diatomaceous earth, calcium silicate, zirconium silicate, zeolite, metal oxide powders, such as aluminum oxides, titanium oxides, iron oxides, or zinc oxides, or mixed oxides of these, barium sulfate, calcium carbonate, gypsum, silicon nitride, silicon carbide, boron nitride, powdered glass, and powdered plastic, for example polyacrylonitrile powders; reinforcing fillers, i.e. fillers whose BET surface area is more than 50 m²/g, for example fumed silica, precipitated silica, carbon black, such as furnace black and acetylene black, and silicon/aluminum mixed oxides of high BET surface area; fibrous fillers, such as asbestos, and also synthetic fibers.

[0070] The fillers mentioned may have been hydrophobicized, for example through treatment with organosilanes or -siloxanes, or with stearic acid, or through esterification of hydroxy groups to give alkoxy groups. Use may be made of one type of filler, or a mixture of at least two fillers may be used.

[0071] If reinforcing silica is used as soles filler, transparent RTV1 alkoxy compositions can be prepared.

[0072] The RTV1 alkoxy compositions preferably comprise at least 2% by weight, in particular at least 5% by weight, and preferably at most 40% by weight, in particular at most 15% by weight, of filler.

[0073] Examples of plasticizers which may be used are alkyl aromatics, or dimethylpolysiloxanes which have end-capping by trimethylsiloxy groups and are liquid at room temperature.

[0074] Aminoalkyl-functional silanes are preferably present as coupling agents. These promote the formation of the tin catalyst (T). Preference is given to silanes of the general formula (X)

A-CH₂)₃—Si(OR¹⁵)₃  (X),

[0075] where

[0076] A is NH₂, NH—CH₂CH₂NH₂, NHR, and glycidoxy, and

[0077] R¹⁵ is as defined for R.

[0078] γ-aminopropyltriethoxysilane is particularly preferred as coupling agent.

[0079] The RTV1 alkoxy compositions preferably comprise from 0.5 to 5% by weight, in particular at most 3% by weight, of coupling agents.

[0080] The invention also provides a process for increasing the storage stability of compositions crosslinkable with elimination of alcohols from alkoxysilyl end groups to give elastomers, in which a tin catalyst (T) is added to the compositions.

[0081] The compositions comprising a tin catalyst (T) have excellent suitability, for example, as sealing compositions for joints, where these include vertical joints, and similar cavities whose gap width is, for example, from 10 to 40 mm, e.g. in buildings, in vehicles used on land or water, and in aircraft, or as adhesives or putties, e.g. in window construction, and also, for example, for the production of protective coverings, or of elastomeric moldings, and also for the insulation of electrical or electronic apparatus.

[0082] In the general formulae (I) to (X), all of the radicals A, L, M, X, Y, R, R¹ to R¹⁵, and also all of the indices b, c, d, f, g, m, n, o, p, r, and p are independent of one another and identical or different.

[0083] In all of the formulae, the silicon atom is tetravalent, as is the tin atom, and the phosphorus atom is pentavalent.

[0084] For the purposes of the present invention, the term organopolysiloxanes is intended to encompass dimeric, oligomeric, and polymeric siloxanes.

[0085] In the examples described below, all of the percentage parts given are based on weight, unless otherwise stated. All of the viscosities given are moreover based on a temperature of 25° C. Unless otherwise stated, the examples below are carried out at the pressure of the ambient atmosphere, i.e. at about 1 000 hPa, and room temperature, i.e. about 20° C., or at a temperature which becomes established when the reactants are combined at room temperature, with no additional heating or cooling.

[0086] Storage stability is determined on the basis of vulcanization of the RTV1 alkoxy compositions (“compounds”) to give elastomers, as a function of storage time. The aging of the “compounds” is accelerated by storage at 50° C. and, respectively, 100° C.

EXAMPLES Example 1

[0087] A reaction product of 1.0 g of dibutyltin diacetate and 2.0 g of tetraethoxysilane is treated with 1.5 g of tributyl phosphate, and the mixture is studied by NMR spectroscopy. In the ¹¹⁹Sn NMR spectrum, a marked high-field shift of the signal is observed and is attributable to complex formation, while the ³¹P NMR spectrum indicates that no P—O—C bonds are cleaved.

Example 2

[0088] 55.4 parts by weight of a polydimethylsiloxane having —OSi(OCH₃) 2 (CH₃) end groups having a viscosity of 80 000 mPas are mixed with 31.2 parts by weight of a polydimethylsiloxane having —OSi(CH₃)₃ end groups (viscosity 100 mPas), and 4.0 parts by weight of methyltrimethoxysilane, in a planetary-gear mixer which can operate in vacuo, water being excluded. 8.0 parts by weight of fumed silica are then incorporated, as are finally 0.8 part by weight of the mixture prepared in example 1. After homogenization in vacuo, the “compound” is drawn off into moisture-proof packs. The result is listed in Table 1.

Examples 3-5

[0089] 55.4 parts by weight of a polydimethylsiloxane having —OSi(OCH₃) 2 (CH₃) end groups having a viscosity of 80 000 mPas are mixed with 31.2 parts by weight of a polydimethylsiloxane having —OSi(CH₃)₃ end groups (viscosity 100 mPas), and 4.0 parts by weight of methyltrimethoxysilane, and 1.0 part by weight of phosphoric ester, in a planetary-gear mixer which can operate in vacuo, water being excluded. 8.0 parts by weight of fumed silica are then incorporated, as are finally 0.4 part by weight of a tin catalyst (reaction product prepared from 4 parts of tetraethoxysilane with 2.2 parts of dibutyltin diacetate). After homogenization in vacuo, the “compound” is drawn off into moisture-proof packs. The phosphoric esters used, and the results, are listed in Table 1.

Comparative Example 6 (Non-Inventive)

[0090] The procedure is as in examples 2-5, except that no phosphoric ester is added. The results are listed in table 1.

[0091] Table 1

[0092] While the “compounds” with phosphoric ester addition vulcanize, with no addition a rubber is not obtained.

[0093] These examples show the suppression of the undesired equilibration process. TABLE 1 Vulcanization P = O Vulcanization after 2 weeks compound after 1 d 100° C. 50° C. Example 2 Product from good good example 1 Example 3 Wacker stabilizer good good S45 (polyglycol ether phosphate) Example 4 Fyrol FR-2*⁾ good good Example 5 Tripiperidino- good good phosphine oxide Comparative — none none example 6

Example 7

[0094] 55.4 parts by weight of a polydimethylsiloxane having —OSi (OCH₃) 2 (CH₃) end groups having a viscosity of 80 000 mPas are mixed with 31.2 parts by weight of a polydimethylsiloxane having —OSi(CH₃)₃ end groups (viscosity 100 mPas), and 4.0 parts by weight of methyltrimethoxysilane, in a planetary-gear mixer which can operate in vacuo, water being excluded. 8.0 parts by weight of fumed silica are then incorporated, as are finally 0.8 part by weight of the mixture prepared in example 1. After homogenization in vacuo, the “compound” is drawn off into moisture-proof packs. The skinning times (ST) are listed in table 2.

Examples 8-9

[0095] 54.4 parts by weight of a polydimethylsiloxane having —OSi (OCH₃) 2 (CH₃) end groups having a viscosity of 80 000 mPas are mixed with 30.5 parts by weight of a polydimethylsiloxane having —Si(OCH₃)₃ end groups (viscosity 100 mPas), and 4.0 parts by weight of methyltrimethoxysilane, and 1.8 parts by weight of a polydimethylsiloxane containing 3-aminopropyl groups, and 1.0 part by weight of phosphoric ester, in a planetary-gear mixer which can operate in vacuo, water being excluded. 7.9 parts by weight of fumed silica are then incorporated, as are finally 0.4 parts by weight of a tin catalyst (reaction product prepared from 4 parts of tetraethoxysilane with 2.2 parts of dibutyltin diacetate). After homogenization in vacuo, the “compound” is drawn off into moisture-proof packs. The phosphoric esters used, and the skinning times (ST) are listed in table 2.

Comparative Example 10 (Non-Inventive)

[0096] The procedure is as in examples 7-9, except that no phosphoric ester is added. The result is listed in table 2. TABLE 2 ST Vulcani- ST after Vulcanization after zation 1 week after 1 Phosphoric 1 d RT after 1 d 50° C. week 50° C. ester [min] RT [min] [min] [min] Example product from 20 good 20 good 7 example 1 Example Wacker 15 good 15 good 8 stabilizer S45 (polyglycol ether phosphate) Example Fyrol FR-2*⁾ 25 good 30 good 9 Compara- — 30 good >180 none tive example 10 

1. [lacuna] with elimination of [lacuna] and which comprise a tin catalyst (T) [lacuna] The invention provides compositions which are crosslinkable with elimination of alcohols from alkoxysilyl end groups to give elastomers, and which comprise a tin catalyst (T), and in which the catalyst present is a tin compound (T) having a coordination number of 5 or 6, in which the tin atom has coordinate bonding to the P═O group of a phosphorus compound having a P═O group, the tin compound (T) being obtainable via reaction of a phosphorus compound having a P═O group and selected from compounds of the general formula (I) O═PR¹ _(m)(OR²)_(n)(OH)_(3-m-n)  (I), where n is the values 2 or 3, if m has the value 0, n is the values 0, 1, or 2, if m has the values 1, 2, or 3, m+n is the values 1, 2, or 3, R¹ and R² are C₁-C₃₀-hydrocarbon radicals, which may have substitution by hydroxy, halogen, or cyano radicals, or radicals of the general formula (II) [(CR³ ₂)_(b)—O]_(c)(CR⁴ ₂)_(d)—L-M  (II), where R³ and R⁴ are a hydrogen radical, methyl radical, or hydroxy radical, b and d are the values 2 or 3, c is integral values from 1 to 15, L is a radical from the group —O—, —COO—, —OOC—, CONR⁵—, —NR⁶CO—, and —CO—, R⁵ and R⁶ are a hydrogen radical or a C₁-C₁₀-alkyl radical, and M is a monovalent C₁-C₂₀-hydrocarbon radical, unsubstituted or substituted with hydroxy, fluoro, chloro, bromo, C₁-C₁₀-alkoxyalkyl, or cyano groups, with the proviso that on each carbon atom only one of the radicals R³ and R⁴ may be a hydroxy radical, compounds of the general formula (III) O═PR⁷ _(o)(NR⁸ ₂)_(p)(OR⁹)_(3-o-p)  (III), where R⁷ is as defined for R¹, R⁸ is as defined for R¹, where it is also possible for the two radicals R⁸ to have bonding to one another, R⁹ is as defined for R¹, or is hydrogen, o is the values 0, 1, or 2, p is the values 1, 2, or 3, and o+p is the values 1, 2, or 3,  and condensates or hydrolysates of compounds of the general formulae (I) to (III) having one or more P—O—P bonds,  with an organic tin compound which is selected from a compound of the general formula (IV) R¹⁰ _(4-r)SnX_(r)  (IV),  a compound of the general formula (V) R¹⁰ ₂SnY  (V),  a compound of the general formula (VI) R¹⁰ ₃SnY_(1/2)  (VI),  and a compound of the general formula (VII) R¹⁰SnY_(3/2)  (VII), where R¹⁰ is C₁-C₃₀-hydrocarbon radicals, which may have substitution by halogen radicals or by cyano radicals, X is halo, —OH, —OR¹⁰, —SR¹⁰, —OOCR¹⁰, —NR¹⁰ ₂, —NHR¹⁰, —OSiR¹⁰ ₃ or —OSi(OR¹⁰)₃, Y is O or S, and r is the values 1, 2, or
 3. 2. A composition comprising a tin catalyst (T), as claimed in claim 1, which is a composition based on compounds having alkoxysilyl end groups, these being organopolysiloxanes, polyethers, polyesters, polyurethanes, polyureas, and copolymers of organopolysiloxanes, polyethers, polyesters, polyurethanes and polyureas.
 3. The composition comprising a tin catalyst (T), as claimed in claim 1 or 2, which is a single-component organopolysiloxane composition crosslinkable with elimination of alcohols to give elastomers (RTV1 alkoxy compositions).
 4. The RTV1 alkoxy composition comprising a tin catalyst (T), as claimed in claim 3, which comprises from 0.01 to 3% by weight of tin catalyst (T).
 5. The RTV1 alkoxy composition comprising a tin catalyst (T), as claimed in any of claims 1 to 4, which comprises aminoalkyl-functional silanes as coupling agents.
 6. A process for increasing the storage stability of compositions crosslinkable with elimination of alcohols from alkoxysilyl end groups to give elastomers, in which tin catalyst (T) as claimed in claim 1 is added to the compositions. 